In n = one RPP, the BA cations interlaced with one another as a result of interaction with apical I atom (shaded as pink) of surface PbI6 octahedron, exactly where a bigger in-aircraft octahedral tilt and a little out-of-aircraft tilt exist. In the case of n = 4 RPP, the BA molecules adopt a “head-to-head” configuration making sure that

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